电压对电刷镀三价铬镀层性能的影响

在45钢表面电刷镀得到三价铬镀层,镀液组成和工艺条件为:Cr2(SO4)36H2O 0.4 mol/L,甲酸铵0.5 mol/L,氨基乙酸0.5 mol/L,H3BO30.6 mol/L,NaH2PO2 H2O 0.3 mol/L,pH=1.5,温度50°C,镀笔移动速率15 cm/s。研究了电压对镀铬层显微结构、表面粗糙度、厚度、显微硬度和耐磨性的影响。随电压增大,镀层厚度增大,显微硬度和耐磨性均先提高后降低。电压为14 V时,镀层的表面平整,粗糙度为2.387μm,显微硬度为602 HV,耐磨性最好。     

分级加载电压下考虑有效电势变化的软黏土电渗固结理论

分级加载电压技术能够有效延长电渗处理的时间,改善地基的处理效果并能有效降低能耗。在利用分级加载电压技术开展电渗试验时,随着土体的排水固结,土体各点的电势会发生明显的变化,这与现有的电渗固结理论假设土体各点电势保持不变有所差异。利用自主设计的电渗试验仪器开展了分级加载电压下的电渗室内试验,分析了电渗过程中土体有效电势变化的规律。基于该规律并结合Esrig固结理论建立了在阳极处不排水、阴极处排水条件下考虑土体有效电势变化的电渗固结理论,得到了分级加载电压条件下考虑土体有效电势变化的超静孔隙水压力和平均固结度的解析表达式。研究表明,在电压分级加载过程中,土体有效电势变化规律表现为随时间先基本保持不变,后呈抛物线状先增后减。通过试验案例验证了考虑土体有效电势变化所求得解析解的合理性,且该数值计算结果相较于Esrig数值计算结果,前者更加接近实测值,该固结方程的建立为后续分级加载电压技术的推广应用提供了理论依据,也为实际工程提供了参考。     

Surface homogenizing heterostructure coatings induced by Ti3C2Tx MXene for enhanced cycle performance of lithium-rich cathode materials

The layered lithium-rich manganese-based cathode material (Li_1.2Mn_0.54Co_0.13Ni_0.13) has the significant advantage of high specific capacity, but this material also suffers serious defects, including severe capacity attenuation and voltage attenuation during the cycle. At present, most researchers have been working to optimize the cycle performance of lithium-rich materials. In this work, we propose a surface homogenizing heterostructure coating induced by MXene modification to reduce capacity reduction and voltage decay. It can be found that the initial Coulombic efficiency (ICE) increases from 77.2% for the bare electrode Li_1.2Mn_0.54Co_0.13Ni_0.13 (LMO) to 85.5% for 1.4 wt% MXene (Ti₃C₂T_x, T_x represents the surface terminations: OH, O, F) modified lithium-rich (TO2). Furthermore, the discharge specific capacity of the electrode at 5 C rate increased from 160.7 mAh g⁻¹ for LMO to 200.6 mAh g⁻¹ for TO2. More prominently, the outstanding cycle stability with capacity retention rate is 82.1% for TO2 after 200 cycles, while only 64.7% for LMO, and the average discharge voltage dropped from 0.788 to 0.468 V. In addition, the mechanism for improving the electrochemical performance is systematically studied.     

Rapid degradation characteristics of an air-cooled PEMFC stack

Durability is one of the obstacles to the large-scale commercialization of proton exchange membrane fuel cell (PEMFC) stacks. Understanding its decay behavior is a prerequisite for improving durability. In this study, rapid degradation characteristics of an air-cooled PEMFC stack are investigated. Due to the simultaneous presence of various degradation sources, the maximum power of the PEMFC stack has been reduced by 39.6% after just 74.6 h of operations. Performance degradation characteristics are sought by analyzing the cell voltage, temperature distribution, ion chromatography, and surface morphology of the gas diffusion layer. The result shows that abnormal cell voltage and temperature distribution can reflect the problematic location. The fluoride ion emission rate is 0.111 mg/day, which proves that the membrane has been seriously degraded. Contact angle reduction and impurities attached to the surface of the gas diffusion layer lead to the water management failure. It is also found that the main factor for performance degradation could be different under different current conditions. And more information can be found under higher current conditions during monitoring the decay of PEMFCs. This study helps to deepen the understanding of performance degradation characteristics.     

A Voltage Control Method for a Distributed Line Feeder by means of Multiagent Approach

This paper proposes a method for the coordinated control of power factor by means of a multiagent approach. The proposed multiagent system consists of two types of agent: single feeder agent (F_AG) and bus agent (B_AG). In the proposed system, an F_AG plays as an important role, which decides the power factors of all distributed generators by executing the load flow calculations repeatedly. The voltage control strategies are implemented as the class definition of Java into the system. In order to verify the performance of the proposed method, it has been applied to a typical distribution model system. The simulation results show that the system is able to control very violent fluctuation of the demands and the photovoltaic (PV) generations.     

Novel dynamic semiempirical proton exchange membrane fuel cell model incorporating component voltages

This paper introduces a novel dynamic semiempirical model for the proton exchange membrane fuel cell (PEMFC). The proposed model not only considers the stack output voltage but also provides valid waveforms of component voltages, such as the no‐load, activation, ohmic, and concentration voltages of the PEMFC stack system. Experiments under no‐load, ramping load, and dynamic load conditions are performed to obtain various voltage components. According to experimental results, model parameters are optimised using the lightning search algorithm by providing valid theoretical ranges of parameters to the lightning search algorithm code. In addition, the correlation between the vapour and water pressures of the PEMFC is obtained to model the component voltages. Finally, all component voltages and the stack output voltage are validated by using the experimental/theoretical waveforms mentioned in previous research. The proposed model is also compared with a recently developed semiempirical model of PEMFC through particle swarm optimisation. The proposed dynamic model may be used in future in‐depth studies on PEMFC behaviour and in dynamic applications for health monitoring and fault diagnosis.     

Estimation of power density in IMPATT using different materials

ABSTRACT

The RF output power dissipated per unit area is calculated using Runge-Kutta method for the high-moderate-moderate-high (n⁺-n-p-p⁺) doping profile of double drift region (DDR)-based impact avalanche transit time (IMPATT) diode by taking different substrate at Ka band. Those substrates are silicon, gallium arsenide, germanium, wurtzite gallium nitride, indium phosphide and 4H-silicon carbide. A comparative study regarding power dissipation ability by the IMPATT using different material is being presented thereby modelling the DDR IMPATT diode in a one-dimensional structure. The IMPATT based on 4H-SiC element has highest power density in the order of 10¹⁰ Wm^?2 and the Si-based counterpart has lowest power density of order 10⁶ Wm^?2 throughout the Ka band. So, 4H-SiC-based IMPATT should be preferable over others for the power density preference based application. This result will be helpful to estimate the power density of the IMPATT for any doping profile and to select the proper element for the optimum design of the IMPATT as far as power density is concerned in the Ka band. Also, we have focused on variation of power density with different junction temperatures and modelled the heat sink with analysis of thermal resistances.     

AlF3-modified LiCoPO4 for an advanced cathode towards high energy lithium-ion battery

Surface-interface reaction between the electrode and electrolyte plays a key role in lithium-ion storage properties, especially for high voltage cathode such as LiCoPO₄ and Ni-riched cathode. Generally, surface modification is an effective method to improve the electrochemical performance of electrode materials. Herein, in order to revise the LiCoPO₄ cathode with desirable properties, uniform AlF₃-modified LiCoPO₄ (LiCoPO₄@AlF₃) cathode materials in nano-sized distribution are synthesized. XRD result indicates that there is no structural transformation observed after AlF₃ coating. TEM characterization and XPS analysis reveal that the surface of LiCoPO₄ particle is coated by a nano-sized uniform AlF₃ layer. Further, the electrochemical results indicate that AlF₃ layer significantly improves the cycling and rate performances of LiCoPO₄ cathode within the voltage range of 3.0–5.0 V. After a series of optimization, 4 mol% AlF₃-coated LiCoPO₄ material exhibits the best properties including an initial discharge capacity of 159 mA h g^?1 at 0.1 C with 91% capacity retention after 50 cycles, especially a discharge capacity of 90 mA h g^?1 can be obtained at 1 C rate. CV curves indicate that the polarization of cathode is reduced by AlF₃ layer and EIS curves reveal that AlF₃ layer relieves the increase of resistance to facilitate Li-ion transfer at the interface between electrode and electrolyte during the cycling process. The enhanced electrochemical performances are attributed to that the AlF₃ layer can stabilize the interface between the cathode and electrolyte, form steady SEI film and suppress the electrolyte continuous decomposition at 5 V high voltages. This feasible strategy and novel characteristics of LiCoPO₄@AlF₃ could promise the prospective applications in the stat-art of special lithium-ion battery with high energy and/or power density.     

基于约瑟夫森量子电压的交流功率测量系统及方法研究

基于约瑟夫森量子电压标准设计了交流功率差分测量系统。通过分析差分采样系统的误差分布及误差传递函数,提出换向差分测量方法,减小了差分采样系统的增益误差,提高了电压幅值测量准确度;通过分析衰减系数η,证明了采用换向差分测量较容易实现10-7量级电压幅值测量。通过评估差分采样系统零相位,结果证明了差分采样系统具有较好的相位测量稳定性。分析了交流功率差分测量系统的不确定度分量,评估了功率因数为1.0,0.5 L和0.5 C时的功率测量不确定度,通过与国家交流功率基准装置进行实验比对,证明了基于约瑟夫森量子电压交流功率测量系统不确定度评估的合理性。     

The vibration and pull-in mechanism of two coupled elastically restrained beams assembly subjected to electrostatic force

ABSTRACT

The novel model of the coupled beam-type electrodes with elastic roots, subjected to the AC and DC voltages is constructed. The exact critical pull-in voltage of the two coupled elastically restrained beams with size effect is presented. The analytical method of the general system subjected to the AC and DC voltages simultaneously is presented. The characteristic mechanism of coupled vibration is investigated.